Sun Multi-Schema XML Validator (MSV) - Java tool to validate XML documents against several kinds of XML schemata. It supports RELAX NG, RELAX Namespace, RELAX Core, TREX, XML DTDs, and most of XML Schema. - https://msv.dev.java.net/
CortexML - Schema management software that provides support for XML versioning, XML Evolution Management (XEM) and centralized schema control. - http://www.ignitexml.com/wildfire/
DTD and Schema Validator - Online validator for checking a W3C XML DTD or schema for conformance to current specifications. - http://www.validome.org/grammar/
Bluetetra XsdDoc - Transforms XML Schema files into cross-referenced, hyperlinked HTML documents and provides a detailed functional report for each schema component. - http://www.bluetetra.com/xsddoc/index.htm
XML Schema validator - Validates XML documents such as XHTML against the appropriate schemas. - http://schneegans.de/sv/
CodeSynthesis XSD - Details of the open-source, cross-platform W3C XML Schema to C++ data binding compiler. - http://codesynthesis.com/products/xsd/
XMLobjective - An XML Schema and XML/XSLT editor. Binding classes generation for XML Schema is supported in C++, Java and RDBs. - http://www.xmlobjective.com
Stylus Studio XML Schema Tools - Tools for visual XML schema editing, conversion, validation, schema documentation generation and XML schema mapping. - http://www.stylusstudio.com/xml_schema.html
dtd2xs - Free tool to translate a DTD into a W3C XML Schema - http://www.lumrix.net/dtd2xs.php
OSS Nokalva XSD Tools - Binds XSD schemas to C/C++ representations; produces XML and binary encodings based on X.694; and validates XSD schemas and XML instances - http://www.oss.com/xml/products/xml.html
XML Validation - Web-based XML validator that produces easy to read error messages and asks for missing files (e. g., XSD) if necessary. - http://xmlvalidation.com
XBinder - An XML Schema to C/C++ data binding tool - http://www.obj-sys.com/products_xbinder.shtml
Pedro - Dynamic form generation, XML Schema, data validation, controlled vocabulary services. - http://pedrodownload.man.ac.uk/
XML Schema Quality Checker - Alphaworks software that takes as input an XML Schema written in the W3C XML schema language and diagnoses improper uses of the schema language - http://www.alphaworks.ibm.com/tech/xmlsqc
XSV: W3C Validator for XML Schema - Web form for checking a schema which is accessible via the Web, and/or schema-validating an instance with a schema of your own. - http://www.w3.org/2001/03/webdata/xsv