Contivo Builder - XML Schema development tool using a vocabulary design model. - http://www.contivo.com/builder/builder.html
TIBCO Turbo XML - Commercial software that provides a design environment for the creation, conversion, and editing of DTDs and various XML schema dialects. Details of features and benefits. - http://www.tibco.com/software/metadata/turboxml.jsp
XMLFox freeware XML/XSD Editor - Freeware graphical XML editing and validation tool for creating valid, well-formed XML documents and/or XSD Schema. - http://www.xmlfox.com
Stylus Studio DTD Tools - DTD editor, DTD Generation, DTD validation, DTD conversion, and industry standard DTD catalog support. - http://www.stylusstudio.com/dtd.html
XSBrowser - Open source browser that creates a human readable document model from a given DTD or XML schema. - http://www.lumrix.net/xsbrowser.php
xmlDraft - an intuitive XML Schema editor, displaying a realtime treeview mockup of what the Instance XML Document should look like while editing the XML Schema - http://www.sysonyx.com/products/xmlDraft/index.asp
Blueprint XML Editor - XML editor and validator of XML documents, DTDs, Relax NG Schemas and XML Schemas. Provides XSLT transformation and preview in built-in browser. Unicode support. - http://www.xmlblueprint.com/
oXygen - XML Editor and XSLT Debugger in Java. Can validate XML, XSD, DTD and XSL. Provides XSLT transformation, Unicode support, FOP support, browser preview, automatic DTD generation, code insight and outliner. - http://www.oxygenxml.com