HTTrack Website Copier - Customizeable web site mirroring tool for Windows and Linux/BSD. [GNU GPL] - http://www.httrack.com/
SiteUpload - A small .NET command-line utility that uploads whole directories to a FTP server. Smart enough to upload only changed files. - http://www.jelovic.com/siteupload
Teleport Pro - Professional website download tool including a GUI and graphical feedback of download progress. Can also understand websites with complex dynamic HTML and Javascript, and be used for offline browsing. - http://www.tenmax.com/teleport/pro/home.htm
WebGet - Downloads files specified in a URL list, which can be in plain text or GetRight format. Designed to be used together with WebSuck (available from the same site) which can extract URLs from web pages. - http://www.ake.nu/software/webget/
GNU wget - GNU mirroring tool which supports http, ftp, proxies, authentication and recursive retrieval of web pages while in the background. - http://wget.sunsite.dk/
W3mir - An all purpose http copying and mirroring tool. - http://langfeldt.net/w3mir/
Rdist - A program to maintain identical copies of files over multiple hosts. - http://www.magnicomp.com/rdist/rdist.shtml
WebLech URL Spider - A web site download tool in Java, which supports many features required to download websites and emulate standard web-browser behaviour. - http://weblech.sourceforge.net/
Sitecopy - For copying locally stored web sites to remote web servers. - http://www.lyra.org/sitecopy/