C# School Book - Free 330-page ebook giving a full introduction to programming in C#, from the very basics to GUI and database development. - http://www.programmersheaven.com/2/csharpbook
C# Book Online - A book that covers all the major aspects of the programming language. - http://www.codereference.com/book/csharp.aspx
Inside C# - By Tom Archer, advertises itself as a detailed look at the internal architecture of C#. - http://www.microsoft.com/mspress/books/5027.aspx
C# Precisely - A concise book describing the C# programming language, version 2.0, including generics, iterators, anonymous methods, nullable value types and partial type declarations. All example programs from the book. Links. - http://www.dina.kvl.dk/~sestoft/csharpprecisely/
Professional C# - Now on its second edition, the book was updated to run on the Final Release of .Net. The book covers C# language syntax, Web Services, Windows Development, ASP, Data Access, .Net Remoting and some concepts of object-oriented programming. - http://www.wrox.com/books/0764543989.shtml